Role of Plant Fibers (PF)s / PF By-products in More sustainable IAD materials Figure 13 Stage 3 of the Contextual Research Factors that Favor Use of PFs for More Sustainable IAD materials Several factors make plant fibers a sensible choice for sustainable IAD materials and products. Many PFs are renewable and sequester carbon during growth, and biodegradable, and many are non-toxic to humans. Many PF are low-cost, lightweight, or have valuable aesthetic properties. [129] Large amounts of plant fibers can be sourced from invasive species or repurposed from agricultural or industrial waste streams. The diversity of plant fibers available worldwide allows for broad application within the IAD sector. This section describes trends, technologies, challenges, and opportunities for using PF in sustainable IAD materials and products.
Evident Trends in the Development and Production of PF-based materials for IAD Traditional Uses of PFs for IAD Applications PF have been used for millennia to build dwellings and community structures, as well as to produce textiles, ropes, rugs, carpets, baskets, and other functional or decorative items. For example, linen, cotton, and hemp have been used to fabricate textiles for curtains, rugs, upholstery, and wall hangings for thousands of years [130] Stronger, more durable fibers like sisal, jute, reeds, and various grasses have been used to make rugs, wall coverings, seats and beds, and ropes. Papyrus, abaca, and rice husks have been used to produce paper and paper pulp products that are used in window coverings, screens, and light fixtures. Many past societies relied heavily on PF for structures, furnishings, and decorative objects. Notably, the Ma’ad people of Iraq engineered complex villages from local reeds and the Uros community on Lake Titicaca in Peru used a local reed to construct homes, floating islands, boats, furniture, baskets, and decorative items. [7] Annex 8 describes various applications of diverse PFs for IAD materials
PF-based Materials and their Modern Applications In the 20th century, rise of steel, concrete and petrochemicals industries undermined the use of natural fiber-based products and and has slowed innovations with plant-based materials. Petrochemical plastics and synthetic fibers became widely popular and soon became ubiquitous across the world, in part because of government lobbying by industry leaders such as Dow Chemicals, ExxonMobil, DuPont, and BASF that yielded government contracts and subsidies that persist today
In response to demand for safer, more sustainable materials, regenerative design, and circular economies, researchers, entrepreneurs, designers and other IAD professionals are pushing PF to the forefront of design. Consequently, some IAD materials based on PF that were once commonplace, but were later superseded by synthetic alternatives, are experiencing a resurgence. In parallel, material designers are developing new composite materials from plant fibers. These include PF-based substitutes for glass or carbon fiber composites used in various IAD applications (insulation, acoustic tiles). [129] Architects who are eager to reduce carbon emissions generated by concrete and insulation are now using the woody inner core of hemp, called hemp hurd, as a breathable, moisture-regulating alternative to conventional concrete and insulation. [131]
PF-based materials from Abundant Sources and Agro-industrial By-products or Waste Streams Designers, scientists and industry professionals recognize the importance of sourcing PF from abundant sources that do not compete for use of arable land and water that are needed to produce food and water for other life-sustaining purposes. For this reason, many focus on PF from agricultural and industrial by-products and waste streams. For example, many have repurposed coconut husks, beer grains, sawdust, and recycled cardboard into concrete, particle boards, acoustic panels, flooring, insulation panels, wall panels, furniture, light fixtures, and other IAD materials. For example, Honext produces wall panels from recycled paper [132] and Biohm is developing modular building systems using a particle board derived from agricultural waste. [133] Leveraging agro-industrial byproducts and wastes can reduce material costs, transform wastes into high value products, boost profits, and diversifying sources of revenue.
Some designers and entrepreneurs are exploring the use of PF of invasive species or that proliferate naturally that do not require the energy, additional water, or soil amendments commonly used with cultivated crops. For example, material designer Nanditha Naia has prototyped several materials using water hyacinth, an invasive grass that chokes rivers in India and other regions [134]. A German company has developed Typhaboard from cattails, an abundant reed that grows quickly and aids in filtration and retention of wetland ecosystems. [135]. Similarly, limiting the harvest of natural PF that protect fragile ecosystems may be needed to avoid environmental damage. Annex 8 details other applications of PF for IAD materials for a comprehensive list of fibers and their IAD applications.
Technologies Employed in the Production of PF-based IAD MaterialsAs PFs gain traction as ingredients for IAD materials, a wide variety of PFs and production techniques are being pursued, including traditional and novel approaches. A wide variety of PFs, (geographic relevance, harvest or collection methods, CO2 absorption capabilities, chemical composition and physical performances) are used in the IAD industry and they are applied to a diverse range of IAD material types and IAD applications. The PFs listed are found in different geographic regions, and have different growing rates, harvesting or collection methods, CO2 absorption capabilities, land, nutrient and water requirements, chemical compositions, and physical properties. Although PFs vary geographic relevance; growing rates; requirements for land, water, and other nutrients; harvest and collection methods; CO2 absorption capability; chemical composition; and physical performances, many PFs can be treated, modified, or manipulated using similar techniques. For example, many of the reagents, binders, additives, and fabrication techniques used to create IAD materials from rice husks or coconut fibers can also be applied to IAD materials made of SB. Table 3 and Annex lists PFs commonly used for IAD applications.
Table 3 Commonly used PFs for IAD Products (o if Byproduct or waste product)
Alfa
Bamboo
Bamboo Leaves Ash º
Banana Tree Stem º
Beer Grains º
Coconut Husk / Fiber º
Coconut Chaff º
Cattail
Corn Husk
Cotton
Cotton Stalk º
Flax
Grass
Hemp Fibers
Hemp Hurd / Shive º
Jute
Jute fabric (Recycled) º
Nettle
Okra bast º
Kapok
Papaya Leaves º
Pine needles º
Pineapple Leaf Fibers º
Palm leaves º
Paper Recycled º
Prosopis Juliflora
Ramie
Reed
Rush
Rice Husk
Rice Husk Ash º
Sawdust or wood waste º
Sisal
Seagrass
Sorghum Bagasse º
Straw(from various plants) º
Sunflower Stem º
Sugarcane Bagasse º
Sugarcane Bagasse Ash º
Textile Waste º
Table 4 Types of IAD Materials
Adobe, Daub, and Cob Mixtures
Straw bales
Concrete-like composites
Fiber-reinforced concrete
Concrete / Cement from PF ashes
Ceramics from PF ashes
Particle board
Fiberboard
Mycelium composites
PF reinforced polymers
Other Composite Materials
Paper & Pulp Products
Woven or knit textiles
Non-woven textiles
Fiber mats
Bio-based plastics
Resins
Oils
Waxes
Dyes
Veneer
Table 5 Categories of IAD Applications
Walls
Flooring
Ceiling tiles
Wall panels
Acoustic panels
Insulation
Doors
Room dividers & screens
Acoustic panels
Window treatments
Furniture
Upholstery
Curtains & bedding
Carpets & Rugs
Decorative items
Packaging
The following sections describe each type of IAD material, PFs, reagents, binders, additives, and fabrication, shaping, and finishing techniques that are commonly used to make this material. Many of the listed materials are composites of mixed composition. Some include synthetic, toxic or non-biodegradable ingredients that are listed in the tables below. These summaries provide technical background that guided the second stage of this project, exploration of the SB-based materials; during this stage, use of toxic and non-biodegradable ingredients was avoided.
PF-based Concrete Alternatives PF-based concrete alternatives are used to build walls, countertops, and permanent furniture like built-in shelves, stairs, and benches. Some of these provide insulation or may be suitable for wall and floor coatings. Straw bale construction involves using large straw blocks to create walls that insulate the building and regulate temperature and humidity. Similarly, adobe, cob, or daub and wattle construction uses mixtures of straw, mud, and water to build insulating walls. Adobe mixtures can also be fashioned into bricks or used for floor insulation. Commercial concrete-like composites, such as Hempcrete, combine PF with natural binders and water to create large bricks or entire walls. PF are also used to reinforce and add bulk to traditional concrete mixtures for constructing building foundations, floors, or walls. When PF are burned to produce energy, the ashes can be an ingredient in cement, concrete mixtures, or ceramics.
Table 6 Adobe, Daub and Cob Mixtures : Ingredients & Techniques
Binders & Additives Fabrication Techniques Cutting & Shaping Techniques Coating & Finishing Techniques
Mud [136][137][138][139]
Mixing
Surface sculpting
Natural pigment coating
Hydrated Lime or Natural Hydraulic Lime [137] [138]
Brick or panel molding*
Surface texturing
Mud and lime coating
Water [136] [137] [139]
Super Adobe Construction*
Mud [REF]
Sand [137]
Cob Construction*
Stucco coating
Natural pigments (minerals) [140]
Daub & Wattle Construction*
Tadelakt coating
Manure [138] [139]
Adobe 3D printing*
Plaster (Gypsum) [141]
Adobe sculpting*
*These fabrication techniques do not refer to the preparation of the mixture itself
Table 7 Straw Bales : Ingredients & Techniques
Binders & Additives Fabrication Techniques Cutting & Shaping Techniques Coating & Finishing Techniques
Binder-free [136]
Straw bundling
Mud & Lime coating
Stucco coating
Plastering
Tadelakt coating
Natural pigment coating
Table 8 Concrete-like Composites : Ingredients & Techniques
Binders & Additives Fabrication Techniques Cutting & Shaping Techniques Coating & Finishing Techniques
Hydrated lime or Natural hydraulic lime [131] [142]
Mixing
Cutting with a mechanical saw
Mud & Lime coating
Water [131] [142]
Brick or panel molding
Surface sanding
Stucco coating
Clay [143]
Plastering
Tadelakt coating
Natural pigment coating
Table 9 Fiber reinforced Concrete : Ingredients & Techniques
Binders & Additives Fabrication Techniques Cutting & Shaping Techniques Coating & Finishing Techniques
Concrete [144] [145]
Mixing
Cutting with a mechanical saw
Synthetic sealing
Cement [146]
Brick or panel molding
Surface sanding
Bio-based sealing [ref]
Sand [146]
Surface texturing
Plastering
Water [146]
Stucco coating
Tadelakt coating
Natural pigment coating
Table 10 Cement / Concrete (from PF Ashes) : Ingredients & Techniques
Binders & Additives Fabrication Techniques Cutting & Shaping Techniques Coating & Finishing Techniques
Cement
Mixing
Cutting with a mechanical saw
Synthetic sealing
Water
Brick or panel molding
Bio-based sealing [147]
Superplasticizer
Plastering
Stucco coating
Tadelakt coating
Natural pigment coating
Table 11 Ceramics (from PF ashes) : Ingredients & Techniques
Binders & Additives Fabrication Techniques Cutting & Shaping Techniques Coating & Finishing Techniques
Kaolin [149]
Mixing
Cutting with a grinder
Glazing
Albite [149]
Molding
Quartz [149]
Oven Drying
Kiln Firing
PF-based Particleboards and Fiberboards Particleboard and fiberboards can be used to build furniture, counter tops, walls, and flooring. They are manufactured in large, flat sheets and often coated with a protective layer to make them resistant to water and wear and tear. PF-based particleboards typically use larger plant fiber particles and are not as strong as PF fiberboards that are usually are made from fibers that have been treated using chemical, enzymatic, or saline solutions. PF-based fiberboards tend to be smoother, denser, and stronger than but more expensive than PF-based particleboards.
Table 12 Particleboard : Ingredients & Techniques
Binders & Additives Fabrication Techniques Cutting & Shaping Techniques Coating & Finishing Techniques
Natural Resin Binders (e.g. Cashew Nut Shell,Euphoria Sap, Dammar, Pine Resin) [150]
Mixing
Cutting with a saw (hand or mechanical)
Lamination (e.g. Melamine)
Bio-based resin binders
Mat forming
Milling with CNC or router
Bio-finishing
Synthetic resin binders [151]
Hot pressing with Hydraulic press
Sanding
Synthetic finishing
Citric Acid Binder [152] [45] [153] [154]
Engraving
Table 13 Fiberboard : Ingredients & Techniques
Reagents Binders Additives Fabrication Techniques Cutting & Shaping Techniques Coating & Finishing Techniques
Chemical Alkaline Solution**
Binder-free [155]
Calcium Carbonate (Limestone) CaCO3
Fiber modification
Cutting with a mechanical saw
Lamination (e.g. Melamine)
Enzymatic Alkaline Solution**
Plaster / Gypsum
Mixing (with or without heat)
Milling with CNC or router
Synthetic finishing
Chemical Alkaline Solution**
Hot pressing with Hydraulic press
Sanding
Bio-finishing
Organsolv Reagents** [156]
Engraving
** These solutions will be discussed further in the Reagents in Summary section below.
PF-based Mycelium Composites Some PF-based composites use mycelium, the filamentous part of fungi, as bonding agents. The mycelium feeds off nutrients and cellular tissues in the PFs and, in the process, bonds the PF together. Once the mycelium has grown throughout the PF substrate, the composite can be dried which kills any viable mycelium and results in a lightweight, water-resistant material that can be used for insulation, acoustic panels, wall panels, room dividers and screens, furniture, lamps and light fixtures, and packaging.
Table 14 Mycelium Composite Materials : Ingredients & Techniques
Binders Additives Fabrication Techniques Cutting & Shaping Techniques Coating & Finishing Techniques
Fomes Fomentarius [157] [158]
Guar gum [158]
Spore cultivation
Cutting with a mechanical saw
Bio-based coating
Trametes Versicolor [158]
Wheat flour [159]
Grain cultivation
Sanding with mechanical sander (this process removes the protective skin)
Ganoderma Resinaceum [158]
Distilled water
Substrate Sterilization
Engraving
Genetically modified mycelium strains [93] [160] [161] [159]
Binder-free [155]
Inoculation
Growth Phase
Mixing
Molding
Drying
PF-reinforced Polymers and Other PF-based Composite Materials PF-reinforced polymers are created by mixing PF with bio-based or petroleum-based polymers. The fibers give volume, strength, and support to the polymer matrix. Materials made of PF-reinforced polymers or other PF-based composites can be layered, molded, pressed, sculpted to create flooring, wall tiles, ceiling tiles, furniture, decorative objects, lamps and light fixtures.
Table 15 PF-reinforced Polymers : Ingredients & Techniques
Reagents Binders Additives Fabrication Techniques Cutting & Shaping Techniques Coating & Finishing Techniques
Chemical Alkaline Solution**
Petroleum plastics [43]
Waxes (e.g. carnauba
Fiber modification
Cutting with a mechanical saw
Lamination
Enzymatic Alkaline Solution**
Biodegradable plastics (e.g. PLA)
Plaster / Gypsum
Mixing (with or without heat)
Milling with CNC or router
Synthetic finishing
Chemical Alkaline Solution**
Bio-resin [162]
Cast, Rotational, or Injection Molding
Sanding
Bio-finishing
Organsolv Reagents** [156]
Rubber [163] [50]
Hydraulic Pressing (with or without heat)
Engraving
Other reagents**
Starches
Extruding
Chitosan [164]
Algae (e.g. Agar, Alginate, Carageen)
Table 16 Other Composite Materials : Ingredients & Techniques
Reagents Binders Additives Fabrication Techniques Cutting & Shaping Techniques Coating & Finishing Techniques
Chemical Alkaline Solution**
Calcium Carbonate
Fiber modification
Cutting with a mechanical saw
Lamination
Enzymatic Alkaline Solution**
Plaster / Gypsum
Mixing (with or without heat)
Milling with CNC or router
Synthetic finishing
Chemical Alkaline Solution**
Cast Molding
Sanding
Bio-finishing
Organsolv Reagents** [156]
Hydraulic Pressing (with or without heat)
Engraving
Other reagents**
Lamination
PF-based Paper & Paper Pulp Products PF can be used to make paper or pulp by treating with chemical or enzymatic alkaline solutions. [165] [166] PF-based paper is typically two dimensional and can be used to create light fixtures and packing materials. Paper pulp products are thicker and are often molded to create three-dimensional shapes. These products can be used to create light fixtures, furniture, decorative interior products, and packaging for IAD materials.
Table 17 Paper : Ingredients & Techniques
Reagents Binders Additives Fabrication Techniques Cutting & Shaping Techniques Coating & Finishing Techniques
Chemical Alkaline Solution**
Binder-free
Clay
Fiber modification
Cutting with scissors or knife
Lamination
Enzymatic Alkaline Solution**
Carboxymetucelulose
Alum Additive
Pulping
Lasercutting
Bio-finishing
Chemical Alkaline Solution**
Natural Dyes (from minerals, fungi, or Plants)
Mixing
Folding
Embossing
Organsolv Reagents** [156]
Mold & Deckle forming
Scoring
Printing
Other reagents**
Couching
Hydraulic pressing
Drying
Table 18 Pulp Products : Ingredients & Techniques
Reagents Binders Additives Fabrication Techniques Cutting & Shaping Techniques Coating & Finishing Techniques
Chemical Alkaline Solution**
Binder-free
Clay
Fiber modification
Cutting with a saw (mechanical or hand saw)
Lamination
Enzymatic Alkaline Solution**
Carboxymetucelulose
Alum Additive
Pulping
Lasercutting
Bio-finishing
Chemical Alkaline Solution**
Natural Dyes (from minerals, fungi, or Plants)
Mixing
Milling with CNC router
Embossing
Organsolv Reagents** [156]
Gypsum or other calcium compounds
Cast Molding
Engraving
Printing
Other reagents**
Hydraulic pressing
Drying
PF-based Yarns, Textiles, and Insulation Mats PF-based yarns are typically made by treatment with alkaline, saline, or hydrogen peroxide solutions or retting, a biologic process in which micro-organisms and moisture disintegrate the PF's cellular tissue and separate the fibers. [167] PF-based yarn is then spun in various ways for knitting or weaving textiles. In contrast, non-woven textiles (also known as bio-leathers or bio-films) are created by bonding fibers together with chemical adhesives and/or mechanical or heat treatments. [168] Woven and knit textiles are used for bedding and curtains and woven, knit, and non-woven textiles can be used for upholstery, room dividers and screens, acoustic panels, insulation, and air filters. The term "fiber mat" is used to describe thick, non-woven textiles that are have low density, open matrices, and are highly compressible. These mats are used for insulation, acoustic absorption, or air filtration.
Table 19 Woven or Knit Textiles : Ingredients & Techniques
Reagents Fabrication Techniques Cutting & Shaping Techniques Coating & Finishing Techniques
Chemical Alkaline Solution**
Fiber modification
Cutting with Knife
Flaring
Enzymatic Alkaline Solution**
Weaving (plain, twill or satin weave) [166]
Cutting with CNC (using a blade)
Bio-bleaching
Other reagents**
Knitting (Weft or Warp knitting) [166]
Pressing
Natural dying
Organsolv Reagents** [156]
Sewing
Screen Printing
Folding
Weaving (with strips)
Table 20 Non-woven Textiles : Ingredients & Techniques
Reagents Fabrication Techniques Cutting & Shaping Techniques Coating & Finishing Techniques
Chemical Alkaline Solution**
Fiber modification
Cutting with Knife
Flaring
Enzymatic Alkaline Solution**
Chemical adhesion
Cutting with CNC (using a blade)
Bio-bleaching
Other reagents**
Mechanical adhesion
Pressing
Natural dying
Organsolv Reagents** [156]
Hot pressing
Folding
Screen Printing
Biological Retting Reagents**
Sewing
Embossing
Bacterial cellulose
Weaving (with strips)
Mycelium
Table 21 Fiber Mats : Ingredients & Techniques
Reagents Fabrication Techniques Cutting & Shaping Techniques Coating & Finishing Techniques
Chemical Alkaline Solution**
Fiber modification
Cutting with Knife
Enzymatic Alkaline Solution**
Chemical adhesion
Cutting with CNC (using a blade)
Other reagents**
Mechanical adhesion
Pressing
Organsolv Reagents** [156]
Biological Retting Reagents**
PF-based biopolymers In this report, the term biopolymer refers to polymers that are derived from renewable agricultural resources such as PF and are fully biodegradable. It does not include other polymers that include organic components plus petrochemicals. Many biopolymers are made from plant cellulose and can be used to create room dividers and screens, coatings and finishes, woven or knit textiles, parts and fasteners, decorative items, and packaging materials. [166]
Table 22 Bioplastics : Ingredients & Techniques
Reagents Fabrication Techniques Cutting & Shaping Techniques Coating & Finishing Techniques
Acetic acid and acetic anhydride sulfuric acid, perchloric acid [44][169]
Acid Hydrolysis
Cutting with a saw (mechanical or hand saw)
Lamination
Cast, Rotational, or Injection Molding
Milling with CNC or router
Bio-based coatings
Calendering
Engraving
Thermoforming
Extruding
PF-based Veneers PF-based veneers are sheet-like materials that are used to cover IAD products, often as alternatives to wood veneer.
Table 23 Veneer : Ingredients & Techniques
Binders & Additives Fabrication Techniques Cutting & Shaping Techniques Coating & Finishing Techniques
Natural pigments
Flattening
Cutting with a knife or saw
Lamination
Drying
Cutting with CNC
Bio-based coatings
Marquetry
Embossing
Dying
PF-based Oils, Resins, Waxes & Dyes Oils, dyes, resins and dyes can be extracted from PFs.
Table 24 Resins : Ingredients & Techniques
Reagents Fabrication Techniques Cutting & Shaping Techniques Coating & Finishing Techniques
Acid Hydrolysis Reagents**
Fiber Modification
Grinding or Sanding
Organolsolv Reagents**[156][44]
Distillation
Table 25 Waxes : Ingredients & Techniques
Reagents Fabrication Techniques Cutting & Shaping Techniques Coating & Finishing Techniques
Fiber Modification
Melting
Shaping
Reagents Used for Fiber Modification Treatments In many cases, PFs must be modified with chemical, enzymatic, or biological treatments that reduce their inherently hydrophilic nature. This inherent characteristic results in poor interfacial interactions between the fibers or the other materials in the material matrix and limit strength and other mechanical properties of paper products, composites, and textiles. These treatments isolate the cellulose fibers by separating or degrading the plant’s pectin, lignin, hemicellulose, waxes, or oils. Some treatments improve the strength, flexibility, elasticity, or softness of the cellulose fibers. [129] [34] [170] [165] The fiber modification treatments differ in their surveillance needs and time requirements, water usage, energy usage, and environmental impact. Some require harsh chemicals while others use harmless, naturally occurring bacteria. It is important to consider these factors when planning for material production and scalability and the consistency of final product and to inform the exploratory phase that involves modifying SB fibers.
Retting Process
Retting is a traditional process whereby naturally occurring bacteria and moisture on plants disintegrate much of the cellular tissues and pectin surrounding the fibrous material from the plant's phloem (i.e., bast-fiber bundles). This process facilitates separation of leaf fiber from stems. Dew retting is performed by leaving the plant stems on the fields for many days as the dew, sun, air, bacteria, and enzymes degrade the tissues. Wet retting is performed by submerging the fibers in water, either in slow-moving streams, lakes, salt or brackish water sources, or tanks. [170]
Organosolv Process
Organosolv is an industrial papermaking process that uses organic solvents to solubilize lignin and hemicellulose in PFs. It is an environmentally benign alternative to kraft or sulfite pulping, which uses harsh chemicals (e.g., sodium hydroxide and [NaOH] sodium sulfide [Na2S]). Organosolv solvents (Table 6) are easily recovered by distillation which reduces effluents into the air or water and unpleasant odors. The lignin that is not needed for paper-making can be recovered through filtration and centrifugation and used for other purposes such as resin production. [156].
Table 26 Reagents for Organosolv
Acetone [156][44]
Methanol [156][44]
Butanol [156] [44]
Ethylene [156][44]
Glycol [156] [44]
Formicacid [156][44]
Aceticacid [156] [44]
Chemical Alkaline Treatments
Alkaline chemicals are used to alter the structure of the cellulose fibers in plants by removing the surface solubilizing the lignin (Table 7 and Table 8). Traditionally, plant fibers were cooked with ashes to create fiber pulp for papermaking. Lime or sodium carbonate (Na₂CO₃) can also be used as an alkaline reagents in papermaking. Today the most commonly used alkaline reagents is sodium hydroxide (NaOH), the main ingredient used for Kraft pulping papermaking process. Sodium hydroxide treatments can be used in conjunction with other reagents such as acetic acid or sodium sulfite. Some sodium hydroxide solutions dissolve the cellulose in order to regenerate fibers from cellulose solutions that are then extruded and spun into yarns that can be woven or knit. [34] . In some cases, PF are subject to other chemical treatments after the alkaline treatment to improve certain fiber properties. [129] [171]
Table 2 Chemical Alkaline Reagents
Sodium Hydroxide (Lye) NaOH [34] [129]
Sodium carbonate (Na₂CO₃) [171]
Ashes [172]
Ethylene [156][44]
Sodium Chlorite NaClO2 [129]
Table 28 Other Reagents (often paired with NaOH treatments)
Stearic acid [129] Stearic acidsolution (+ ethanol)
Potassium Permanganate(+acetone) Potassium permanganate [129]
Saline solution [129] [173] (3-glycidyloxypropyl) trimethoxysilane
Acetic acid solution Acetic acid [129]
Benzoyl chloride [129] solution
sodium sulfide [174]
Hydrogen Peroxide solution [155]
Ferrous Sulfate (FeSO4) [155]
Kraft Pulping Process
Kraft pulping is a type of alkaline treatment in which PFs are cooked in a solution of caustic soda and sodium sulfide. This process yields a fiber pulp with great mechanical strength that can be used for packaging. Tall oil is a byproduct of kraft pulping that can be used as an adhesive, cement binder, and other purposes. [174] [166]
Sulfite Pulping and Sulfite Treatments
PFs are treated with an acid bisulfite solution to make paper pulp from wood. The solution softens the wood by isolating the cellulose and solubilizing the lignin. The process creates sulfur dioxide and will corrode metal so must be performed in acid- resistant lined vessels. [175]
Enzymatic Treatments
Enzymatic treatments are becoming increasingly popular as more environmentally friendly alternatives to chemical treatments for degrading the lignin in PFs. Some enzymes are used for softening or strengthening fibers; others are used for bleaching fibers (Table 9) and paper pulping. Some enzyme solutions are alkaline and work like alkaline chemicals to degrade lignin. Other enzymes such as lipase or pectinase degrade the oils and pectin in plants tissues. Typically, several different enzymes are mixed together in solutions to to achieve desired results. [165] [176] [177] [178]
Table 29 Enzymatic Reagents / Catalyzers
Laccase [176] [179] [177] [178]
Lignin Peroxidase [176] [177] [178]
Saline solution [129] [173] (3-glycidyloxypropyl) trimethoxysilane
Glucose oxidase [177]
Aryl alcohol oxidase [178]
Xylanase [179]
Mannanase [179]
Lipase [165]
Pectinase
Acid Hydrolysis
Acid hydrolysis is a chemical process that involves breaking down complex molecules into simpler components using acids as catalysts. It can be used to break down the lignin, hemicellulose and cellulose in plant fibers to regenerate cellulose fibers. Additionally acid hydrolysis plays a crucial role in transforming natural polymers like cellulose into useful biomaterials like cellulose acetate. [44] [180] [169]. This process is not commonly used for papermaking because it will often weakens the cellulose fiber pulp.
Table 30 Reagents for Acid Hydrolysis
Hydrochloric acid [169]
Sulfuric acid [169]
Triflouroacetic acid [169]
Formic acid [169]
Nitric acid [169]
Acetic acid [44]
Acetic anhydride [44]
Perchloric acid [44]
Overview of Bio-based Binders Bio-based binders such as starch, chitin, algae, or mycelium have the potential to play a pivotal role in developing sustainable IAD materials because they are derived from natural, renewable sources sourced from diverse regions of the world and are safer and more sustainable than synthetic petro-chemical binders. These binders are sourced from different geographic regions, and vary in molecular composition and mechanical properties. Most binders are biodegradable, home compostable, or compostable in an industrial facility although the conditions and rates of biodegradation vary. All of these factors should be taken into account when selecting a binder for PF-based material development. Annex 12 lists and describes commonly used bio-based binders.
Overview of Bio-based Additives Incorporating additives into bio-based composites can yield various attributes that enhance the materials' overall functionality, durability, and sustainability. Favorable attributes include improved water repellency, mechanical strength, electrical conductivity, fire resistance, insulation, structural integrity, or antimicrobial activity. Bulking additives can also act as fillers to increase material volume. Annex 13 describes commonly used additives.
Overview of Bio-based Material Fabrication Methods Many techniques are used to fabricate bio-based materials (Table 11). Fabrication results can vary greatly depending on the quality and precision of the available equipment. Some processes require simple devices that grind, blend, dry, or heat components that are often found in many home kitchens. Others processes employ expensive devices, like weaving looms, injection molding equipment, or thermo-hydraulic presses, but sometimes simple, inexpensive alternatives like cardboard looms, syringes, hand-made molds, and clothing irons can be used during exploratory phases. Although high-performance, homogenous materials can be difficult to create using simple, inexpensive devices, early testing with low-cost, accessible tools allows material designers to explore materials and fabrication techniques before investing in expensive equipment or collaborating with a factory or a laboratory. Many devices that have been used to create IAD products from non-sustainable materials like petroleum-based plastics and concrete can be adapted for sustainable materials like bioplastics, thereby extending the life-span of the equipment.
Table 31 Identified Material Fabrication Techniques
Fiber modification treatment
Mixing (with heat or without heat)
Thermoforming
Molding (cast, rotational, injection, compression,brick & panel molding)
Flattening
Grinding (dry ingredients using a blender orprocessor)
Pressing (with a hydraulic press)
Drying (air drying, oven drying, or dehydration)
Extruding
Mycelium composite techniques (cultivation,sterilization, inoculation, growing)
Blending (with wet ingredients using a blender)
Thermo-pressing (with a hydraulic press)
Cooling
Calendering
Kiln firing
Pulping
Lamination
3D printing
After materials are created, they may require milling, sanding, cutting, bending, shaping, or engraving using one or more techniques (Table 32). To enhance durability or aesthetic values, some materials may also need surface finishing or coating using various methods (Table 33).
Table 32 Identified Cutting and Shaping Techniques
Surface sculpting
Cutting (hand saw or mechanical saw)
Sanding / Shaping
Patterning & Sewing
Scoring
Surface sanding
Cutting (with knife or CNC cutter)
Folding
Marquetry
Engraving
Surface polishing
Table 33 Identified Coating and Finishing Techniques
Natural pigment coating
Mud & Lime coating
Plastering
Stucco
Tadelakt
Surface sanding
Synthetic sealing
Glazing
Lamination
Embossing
Printing
Flaring
Dying
Challenges with Developing and Employing PF-based Materials for IAD applicationsMany of the challenges for developing and using sustainable and bio-based IAD materials (Section 5.1.2.4) also apply to PF-based materials. Use of PF-based materials for IAD applications may also pose unique challenges as described below.
Raw material, Energy and Water Usage The vegetative volume, energy and water needed for cultivation, harvesting, storage, and shipment will vary by type of PF. Some fibers necessitate active cultivation and harvesting, which can incur significant costs for water, fertilizer and pesticide dispersion, labor, and machinery as well as storage and transport that in turn may generate carbon emissions. For instance, cultivation of organic cotton, a popular choice for upholstery and other textiles often requires large amounts of water. This demand can result in local conflicts about water use and rights in cotton growing nations such as Egypt. [181]
However, when PFs are obtained from invasive species or are byproducts or waste from agricultural or industrial processes, the energy and water demands are significantly diminished, resulting in lower carbon emissions. [148] However, establishing sustainable and scalable partnerships with waste producers that require efficient communication, clear protocols, and regular pickup intervals may take time and effort to implement.
Producers of many composite PF-based materials must source binders, additives, and other ingredients such as biopolymers, minerals, natural pigments, oils or waxes. Some of these ingredients, especially natural ones, may be difficult or costly to access, especially in regions where they are not grown, not produced or are exported for use in other countries.
In addition, there is a risk that using PF or plant-based binders or additives may encourage monoculture practices, especially when the needed plant is not native to the region. Monoculture of soy beans, oil palms, corn and sugarcane have caused immense deforestation across the globe. Finally, starting cultivation of new plant species needed for PF-based materials in new locale can lead to invasion and degradation of local ecosystems. For example, many invasive reeds and grasses, such as water hyacinth and bamboo that spread rapidly and can potentially threaten natural ecosystems. [182] [183]
Regulatory Compliance PF-based materials must comply with specific industry standards to be deemed suitable for IAD applications. As discussed in section 5.1.2.4 Challenges of developing and employing sustainable and bio-based materials for IAD , adherence to these standards necessitates specialized testing which can only be performed in well-equipped labs or industrial facilities and skilled personnel. These testing costs can be prohibitive, especially if several prototypes with varied compositions need testing.
There are particular certifications tailored for PF-based materials that can increase their market appeal. In response to the burgeoning demand for sustainable, fair-trade, and recycled products, some organizations have developed certifications specific to PF-based materials. For example, Oeko-Tex [111] has a program to certify sustainable or bio-based textiles and the Forest Stewardship Council (FSC) [125] for certifies sustainable paper products. Although these certifications provide a valuable endorsement that can increase market appeal, they may require extensive and costly testing as well as regular inspections by members of the certifying boards.
Economic and Technological Hurdles Access to infrastructure and manufacturing facilities is a crucial for research and scaling up production of PF-based materials. Typically, many high-income countries offer affordable access to a diverse range of machinery and tools required for the production and testing of PF-based materials, but these resources may be difficult to find or afford in low and middle-income countries, including ones in rural or tropical regions that often produce high volumes of PF that may have potential for IAD materials When PFs are grown in rural areas or remote from material testing and production facilities, costs and carbon emissions associated with transport, shipping, and storage increase.
Market Acceptance and Navigating Markets Distorted by Greenwashing One significant challenge is convincing architects, designers, and construction firms to incorporate materials made of natural fibers in their work, particularly if the durability and longevity of these materials is uncertain or known to be less than petroleum-based materials. Some PF-based products may be susceptible to termite infestation, mold, and water damage which can discourage adoption. [184] Use of PF-based products that necessitate frequent replacement or repair that require energy or water or emit carbon can also increase their environmental impact
Additionally, the IAD industry markets many products that purport to be "eco-friendly" or made from natural fibers and binders but actually contain binders or other ingredients made from petroleum-based plastics or other substances that may harm the environment. Moreover, production of some "eco-friendly" or recycled PF-based materials may use more energy, waters, or chemicals or emit more carbon than production using raw or virgin materials. [9] For example, the production of some recycled paper can consume more energy, water or chemicals than creating paper products from virgin wood pulp. Greenwashing can mislead or confuse consumers and investors. In some cases, publication of an accurate and clear product life cycle assessment is needed to compare the environmental consumption and impact of PF-based materials with traditional alternatives, accurately represent these products on the market, and reduce confusion.
Ethical Concerns and Social Challenges A significant portion of natural fiber products, including textiles and furniture, are produced in low- or middle-income countries of the Global South by workers who suffer unjust or inhumane working conditions. As demand for sustainable products in high-income countries surges, there is a concern that such production will perpetuate or accelerate unfair, exploitative labor practices and social disparities in the Global South. For example, many textile workers and basket weavers who make IAD products with machines or by hand receive only a small fraction of profits when these products are sold at remarkably low prices in high-income countries.
In many regions of the world, the harvest of plant fibers for food or product development involves intense working conditions, e.g., long hours and exposure to intense sun or rain, insects, pesticides, and other potentially harmful conditions. For example, cotton production in Uzbekistan and other countries has induced complaints about forced labor and child labor during harvesting. [185] In Malaysia, Indonesia, and Brazil palm oil production has been linked to poor working conditions, violations of rights of workers or indigenous communities, land disputes, and deforestation. [186]. [187]
In addition, some designers or IAD professionals who visit artisan communities, including found in low- and middle-income countries and indigenous groups, study the unique techniques, patterns, and styles of their products and later produce copies of these products at large scale in factories and sell them for low prices. These practices undermine the value of artisanal products, the economic viability of local artisans, and the preservation of culturally significant techniques. Ethical dilemmas can also arise when consultation or approval of artisan communities is not sought before their artistic and cultural heritage is appropriated for mass production.
Opportunities in Developing and Employing PF-based materials for IADThe development and application of sustainably made IAD materials present numerous opportunities for economic and technological development as well as more environmentally and socially sustainable practices. Many of the opportunities described in section 5.1.2.4 Challenges of developing and employing sustainable and bio-based materials for IAD apply to the development and production of PF-based materials. Use of PF-based materials for IAD applications may also pose unique challenges as described below. This section elaborates on opportunities that are specific to the use of of PF-based materials.
Possible Resource Reductions, Localization, and Reduced Carbon Footprint Unlike most synthetic materials derived from finite resources such as petroleum, most plant fibers are renewable. Many can be grown repeatedly over relatively short time periods. As plants grow, they absorb CO2 from the atmosphere, a process that can effectively sequester carbon emissions for various man-made sources. If sustainable agricultural practices are used, some adverse environmental impacts of cultivation can be minimized. The extraction and processing of PF typically require less energy than the extraction and processing of petroleum products, minerals, or stones that are obtained through drilling, mining, or other excavation methods. PF and plant byproducts and waste streams that could be used for IAD materials are widely available in all regions of the world. This diversity that enables development and use of local materials that may require less transport, storage, and emitted carbon. Finally, local solutions are key as communities and governments try to promote local economies that are linked to our natural ecosystems and reduce carbon emissions associated with transport.
The use of non-woody PF that grow very fast in a diverse range of climates and require little care (e.g., bamboo, cattails) can reduce some demand for virgin wood and timber harvesting for wood products such as framing, flooring, particleboard, fiberboard, and furniture used in the IAD industry. Wood is in high demand as architects adopt sustainable pledges and use more and more CLT or build mass-timber structures. Thus, it is important to take the burden off wood when possible.
Using PF from byproducts and waste streams for IAD materials can dramatically reduce use of land, water, and energy sources that emit carbon as compared with using newly cultivated PF or virgin timber. In many low- and middle-income nations, disposal of agricultural crop wastes such as SB, wheat straw, and husks of rice and coconut is a significant problem. [148] It is estimated that approximately 450 metric tons of agricultural waste is produced annually. [188] The most common strategies to manage such agrowastes include dumping in landfills (which reduces land for more productive uses), incineration (which emits atmospheric CO2 and pollutants), and composting which can enrich soil nutrients and water retention. [189] As the global agricultural sector expands to feed an ever-increasing population, many countries will need to exploring novel ways to use PF byproducts and waste materials and other agrowastes.
Increasing Public Interest and Demand for Sustainable IAD Alternatives and Market Growth and Diversification Most PFs are non-toxic to humans and the environment. Material safety is particularly important for the IAD industry that creates environments in which people spend most of their lives, e.g., homes, schools, offices, factories, and other interiors. As more customers become aware of the need for good indoor air quality and preventing off-gassing of chemicals from carpets, textiles, cabinets, furniture, and other IAD materials that can cause "sick building syndrome", interest in non-toxic and plant-based materials has grown. For example, Deloitte’s UK survey on consumer attitudes and behaviors around sustainability revealed that increasing consumer interest in sustainability has become manifest in preferences for household items and beauty products, brands that indicate more environmentally sustainable or ethical values and practices, and avoidance of single-use plastics. But 52% of the survey participants stated that adopting a sustainable lifestyle is too expensive. [190] Large brands like Zara Home have responded to this consumer interest in natural materials as they market furniture, upholstery, linens, carpets, baskets, and other decorative items made from cane, bamboo, rattan, wicker, and other PF. [191] However, marketing of IAD materials that stresses consumerism, keeping up with new trends, frequent renovations and disposal of IAD materials can lessen the potential environmental benefits of PF-based products and increase the costs of adopting a more sustainable lifestyles. [190]
More positive consumer attitudes about using byproducts or wastes in IAD products may promote use of these materials in lieu of virgin materials. Many consumers who once regarded use of byproducts and wastes as dirty or indicative of poverty now regard these materials as "sustainable", "responsible", or less costly alternatives. Some designers and design firms are highlighting their use of PF byproducts and wastes in leading IAD magazines (e.g., Dezeen and Arch Daily) and international exhibitions (e.g., Design Weeks in Italy and the Netherlands). [192] [193] [32] More IAD firms have made pledges to apply net-zero, zero-waste or circular design approaches; are hiring "sustainability experts" to encourage use of more environmentally friendly materials; and are teaching staff, clients, and colleagues about material choices from renewable PFs, agricultural byproducts or waste materials to reach their sustainability goals.
Recent estimates predict substantial growth in the global markets for "ecofibers" (projected to grow by 7.8% between 2022 and 2030 [194] and natural fiber composite industries (projected to grow at a rate of 11.8% between 2018 and 2024) that serve the IAD industry. This growth is likely to continue due to consumer and investor interest in "green" and "eco-friendly" products and technical advances in these product sectors. [195]
Innovation and Technical Advances Several technical advances allow use of PFs in ways that could apply to the IAD industry. Recent advances in composite technology have enabled the use of PF-based composite materials. Some of these have been shown to be 25-30% stronger than glass fiber composites, to consume less energy to fabricate, and to reduce production costs by 10%. [195]. The use of nano and micro technologies to extract cellulose from virgin PF and PF byproducts and agrowastes has been an important development. Cellulose nanofibers and micro-fibrillated cellulose are very strong and can be used in a variety of applications, e.g., making stronger paper products and reinforcing bioplastics. [196]
New bio-binders using natural polymers or bio-resins have been developed that can be combined with PF to make durable and sustainable composite materials. Much research has focused on lignin, a natural and biodegradable binder found in many plants. Because the phenolic polymers of lignin provide structural support and are non-toxic and biodegradable, they offers an "eco-friendly" substitute for phenol-formaldehyde adhesives that, if off-gassed, can cause respiratory irritation. Researchers have identified several application for these lignin polymers, such as adhesive in plywood, fiberboard and particleboard and as a binder in printed wiring boards, abrasive tools, epoxy asphalts, epoxy wood composites, 3D printing, adhesive hydrogels, lignocellulosic paper, and coatings. [197] Polylactic Acid (PLA) is compostable under controlled conditions. Other innovative bioplastics include compostable polyethylene furanoate (PEF), biodegradable Bio-PBS (biopolybutylene succinate), and fully biodegradable polyhydroxyalkanoates (PHA). Other novel bio-based polymers made from renewable sources such as (bio-PET), bio-polyethylene (bio-PE), or bio-polyamides (bio-PA or nylon) are less promising as long-term solutions becausee they are not biodegradable. [198]
Plant based resins and filaments are now being used with 3D printing technology that has the potential to produce IAD products on demand or with complex shapes. Wood PLA composite 3D printer filament has also gained popularity for making small scale models or parts. [199] Designers and architects have also used 3D printing at scale using PF, agricultural waste, and other natural and biodegradable materials. For example, a team of students and architects at Institute of Advanced Architecture of Catalonia (IAAC) printed a 3D house using an adapted adobe mixture. [101]
Advances in chemical and enzymatic treatments have improved the performance of plant fibers, making them more resistant to moisture, pests, and other environmental factors. In some cases, enzymatic treatments have replaced harsh alkaline or acid treatments to modify the surface of the PF that can enhance compatibility in composite production, paper strength, and non-woven textile production. [165] [178] [177] [179] [176]
Finally, innovations in biotechnology have potential for future IAD applications. For example, laboratories have produced genetically modified organisms with increased yield or other desirable properties as well as genetically modified plants, algae, and fungi to improve certain characteristics of these natural binders. For instance, mycelium of fungi can be genetically modified to create a stronger bonding agent.
Regulatory Incentives and Funding More industries and governments have mandated "green" building codes. some of which require use of PF-based materials for insulation mats, composite materials, flooring, and wall and ceiling panels. In addition to the tax incentives, government legislation and funding opportunities mentioned in Section 5.1.2.4 Challenges of developing and employing sustainable and bio-based materials for IAD, some government organizations award grants to develop sustainable materials from PF or biomass waste streams. In the EU, the Horizon 2020 program supports research on renewable resources, including those related to
Long-Term Sustainability and Promotion of Circular and Regenerative practices A material or product is not only considered sustainable or circular because of its material ingredients or its biodegradability. The sustainability of a PF-based material can be enhanced if it is biodegradable and it is sourced and produced using regenerative, economically viable, and ethically sound methods. Use of regenerative agriculture, protection of land rights and worker rights, efficient energy and resource utilization, and manufacturing optimization are some examples of practices that can make a product more sustainable.
Regenerative agriculture practices include rotation of diverse crops (instead of monoculture), using cover crops, fertilizing with compost and manure, minimizing tilling and ploughing, applying agroforestry techniques, and integrating livestock grazing. These practices improve overall soil health that can increase crop yields, produce more nutritious food, store more carbon, and increase biodiversity. Agroforestry is multilevel farming method in which diverse plants and trees are simultaneously cultivated in a self-sufficient ecosystem that provides complementary nutrients in the plants and soil. Using agroforestry techniques, many PFs that can be used for IAD materials (Table 3 in Section 5.1.3.3 ) can be cultivated along with cassava, potatoes, corn, and other plants that can be harvested for starch-based material binders/biopolymers.
In some cases, plant byproducts and agricultural wastes can be used for making IAD materials. For example, pineapple farmers in Indonesia sells discarded leaves to the Ananas Anam’s company that makes biodegradable textiles, including a leather-like product for furnishings. This additional revenue source also provides economic, social, and ecological benefits to these farming communities.